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How does acetone reacts with HCN and NaHSO3?

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Match the properties given in Column I with the metals given in Column II.

 
Column I (Property)
 
Column II (Metal)
(i)
An element which can show +8 oxidation state
(a)
Mn
(ii)
3d block element that can show upto +7 oxidation state
(b)
Cr
(iii)
3d block element with highest melting point
(c)
Os
   
(d)
Fe

 

For the complex [NiCI4]2-, write

  1. The IUPAC name.
  2. The hybridization type.
  3. The shape of the complex.

(Atomic no. of Ni = 28)

  1. Urea forms an ideal solution in water. Determine the vapour pressure of anaqueous solution containing 10% by mass of urea at 40°C. (Vapour pressure of water at 40°C = 55.3 mm of Hg)
  2. Why is freezing point depression of 0.1 M sodium chloride solution nearly twice that of 0.1 M glucose solution?
Define the following with a suitable example in each:
  1. Oligosaccharides
  2. Denaturation of protein
  3. Vitamins
What is Isotonic, hypertonic and hypotonic Solution?
Define the following terms as related to proteins:
  1. Peptide linkage.
  2. Primary structure.
  3. Denaturation.
A 4% solution (w/w) of sucrose (M = 342 g $ mol^{-1} $) in water has a freezing point of 271.15 K. Calculate the freezing point of 5% glucose (M = 180 g $ mol^{-1} $) in water. (Given: Freezing point of pure water = 273.15 K)
An alkene ‘A’ (Mol. formula C5H10) on ozonolysis gives a mixture of two compounds ‘B’ and ‘C’. Compound ‘B’ gives positive Fehling’s test and also forms iodoform on treatment with I2 and NaOH. Compound ‘C’ does not give Fehling’s test but forms iodoform. Identify the compounds A, B and C. Write the reaction for ozonolysis and formation of iodoform from B and C.
Calculate the molarity of 250 mL solution made by dissolving 5 g NaOH in water.