$CH_3CH=CHCH_2CHBrCH_3$
$CH_3CH=CHCH_2CHBrCH_3$
Number of optical isomers $=2^{n}$
where, $n=$ number of asymmetric carbon atoms
$2^{1}=2$
Number of geometrical isomers $=2^{n}$ where, $n=$ number of double bonds $=2^{1}=2$
Hence, total number of stereoisomers $=$ Total optical isomers $4\,-$ Total geometrical isomers
$=2+2=4$
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| Exp. | $[A]\,(mol\,L^{-1})$ | $[B]\,(mol\,L^{-1})$ | Initial rate $(mol\,L^{-1}\,s^{-1})$ |
| $1.$ | $2.5\times 10^{-4}$ | $3\times 10^{-5}$ | $5\times 10^{-4}$ |
| $2.$ | $5\times 10^{-4}$ | $6\times 10^{-5}$ | $4\times 10^{-3}$ |
| $3.$ | $1\times 10^{-3}$ | $6\times 10^{-5}$ | $1.6\times 10^{-2}$ |
$\mathrm{Cd}_{(s)}+\mathrm{Hg}_{2} \mathrm{SO}_{4(s)}+\frac{9}{5} \mathrm{H}_{2} \mathrm{O}_{(l)} \rightleftharpoons \mathrm{CdSO}_{4} \cdot \frac{9}{5} \mathrm{H}_{2} \mathrm{O}_{(s)}+2 \mathrm{Hg}_{(l)}$
The value of $\mathrm{E}_{\text {cell }}^{0}$ is $4.315\, \mathrm{~V}$ at $25^{\circ} \mathrm{C}$. If $\Delta \mathrm{H}^{\circ}=-825.2\, \mathrm{~kJ} \,\mathrm{~mol}^{-1}$, the standard entropy change $\Delta \mathrm{S}^{\circ}$ in $\mathrm{J} \,\mathrm{K}^{-1}$ is ........ . (Nearest integer) [Given : Faraday constant $=96487\, \mathrm{C}\, \mathrm{mol}^{-1}$ ]