MCQ
Hydrogen bonding is maximum in
- ✓${C_2}{H_5}OH$
- B$C{H_3} - O - C{H_3}$
- C${(C{H_3})_2}C = O$
- D$C{H_3}CHO$
Hydrogen bonding is observed when $H$ atom is attached to more electronegative $N , F$ or $O$ atom.
Thus, hydrogen bonding is possible in ethanol and triethylamine.
In ethanol, $H$ is attached to a more electronegative oxygen than in triethylamine, in which $H$ is attached to a less electronegative nitrogen.
Moreover, in triethyl amine, the $+ I$ effect of three methyl groups decreases the extent of hydrogen bonding.
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| List $-I$ | List $-II$ |
|
$A.$ Melting point $[\mathrm{K}]$ |
$I.$ $\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}>\mathrm{Al}>\mathrm{B}$ |
|
$B.$ Ionic Radius $\left[\mathrm{M}^{+3} / \mathrm{pm}\right]$ |
$II.$ $\mathrm{B}>\mathrm{Tl}>\mathrm{Al} \approx \mathrm{Ga}>\mathrm{In}$ |
| $C.$ $\Delta_{\mathrm{i}} \mathrm{H}_1 $ $ [\mathrm{~kJ} \mathrm{~mol}^{-1}]$ | $III.$ $\mathrm{Tl}>\mathrm{In}>\mathrm{Al}>\mathrm{Ga}>\mathrm{B}$ |
| $D.$ Atomic Radius $[pm]$ | $IV.$ $\mathrm{B}>\mathrm{Al}>\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}$ |