- A$Zr - Ta$
- B$Nb - Tc$
- C$Hf - Re$
- ✓$Nb - Ta$
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$‘A’$ in above reaction is

image $\xrightarrow{{[O]}}A\xrightarrow{{SOC{l_2}}}B\xrightarrow{{Na{N_3}}}C\xrightarrow{{{\text{Heat}}}}D$
Assertion $A$: Permanganate titrations are not performed in presence of hydrochloric acid.
Reason $R$ : Chlorine is formed as a consequence of oxidation of hydrochloric acid.
In the light of the above statements, choose the correct answer from the options given below.
$(a)$ $NCl_3$ is formed when $Cl_2$ is present in excess.
$(b)$ $N_2$ is formed when $Cl_2$ is present in excess.
$(c)$ $N_2$ is formed when $NH_3$ is present in excess.
$(d)$ $NCl_3$ is formed when $NH_3$ is present in excess.
Correct option are