B = Cu(NO3)2
C = [Cu(NH3)4](NO2)2
D = CO2
E = CaCO3
F = Cu2[Fe(CN)6]
G = Ca(HCO3)2
$\text{CuCO}_3\rightarrow\text{CuO}+\text{CO}_2\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^{\text{(D)}}$
$\text{CuO}+\text{CuS}\rightarrow\text{Cu}+\text{SO}_2\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^{\text{(A)}}$
$\text{Cu}+\text{4HNO}_3\text{(Conc.)}\rightarrow[\text{Cu(NO}_3)_2+2\text{NO}+2\text{H}_2\text{O}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{(B)}$
$\text{Cu}^{2+}+\text{NH}_3\rightarrow[\text{Cu(NH}^3)^4]\\ \ \ \ ^\text{(B)} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{(C)}$
$\text{Ca(OH})_2+\text{CO}_2\rightarrow\text{CaCO}_3+\text{H}_2\text{O}\\ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{(D)} \ \ \ \ \ \ \ \ \ \ \ \ \ ^\text{(E)}$
$\text{CaCO}_3+\text{H}_2\text{O}+\text{CO}_2\rightarrow\text{Ca(HCO}_3)_2$
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| Experiment | $[ A ] / mol L ^{-1}$ | $[ B ] / mol L ^{-1}$ | Initial rate of formation of D $/ mol L ^{-1} min^{-1}$ |
| I | 0.1 | 0.1 | $6.0 \times 10^{-3}$ |
| II | 0.3 | 0.2 | $7.2 \times 10^{-2}$ |
| III | 0.3 | 0.4 | $2.88 \times 10^{-1}$ |
| IV | 0.4 | 0.1 | $2.40 \times 10^{-2}$ |
Match the graph given in Column I with the order of reaction given in Column II. More than one item in Column I may link to the same item of Column II.
Column I | Column II | ||
(i) | ![]() | ||
(ii) | ![]() | (a) | Ist order |
(iii) | ![]() | (b) | Zero order |
(iv) | ![]() |