$M=[\mathrm{Ar}] 3 \mathrm{d}^{10} 4 \mathrm{s}^{2} 4 \mathrm{p}^{1}$
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$C{H_3} - \mathop {\mathop {N\, - \,}\limits_{|\,\,\,\,\,\,} }\limits_{C{H_3}} \mathop {\mathop {C\,\,\, - }\limits_{|\,\,\,\,\,\,\,}^{|\,\,\,\,\,\,\,} }\limits_{{C_2}{H_5}}^{C{H_3}} C{H_2} - C{H_3}$
$CH_3CH_2CH_2CONH_2$ $\mathop {\xrightarrow{{Ca{{(OH)}_2},C{l_2}}}}\limits_\Delta X\xrightarrow{{HN{O_2}}}Z$
Statement $(I)$ : $A$ Buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities.
Statement $(II)$ : Blood is naturally occurring buffer solution whose $\mathrm{pH}$ is maintained by $\mathrm{H}_2 \mathrm{CO}_3 / \mathrm{HCO}_3$ concentrations.
In the light of the above statements, choose the correct answer from the options given below.