MCQ
(image) $\xrightarrow{{Conc.\,HN{O_3}}}$ Product is


- A$o-$ nitrophenol
- B$p-$ nitrophenol
- C$m-$ nitrophenol
- ✓Picric acid

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$C{H_3}CN\xrightarrow{{Na + {C_2}{H_5}OH}}X\xrightarrow{{HN{O_2}}}Y\mathop {\xrightarrow{{{K_2}C{r_2}{O_7}}}}\limits_{{H_2}S{O_4}} Z$
| Column $I$ | Column $II$ |
| $(A)$ $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{CN}$ | $(p)$ Reduction with $\mathrm{Pd}-\mathrm{C} / \mathrm{H}_2$ |
| $(B)$ $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OCOCH}_3$ | $(q)$ Reduction with $\mathrm{SnCl}_2 / \mathrm{HCl}$ |
| $(C)$ $\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}_2 \mathrm{OH}$ | $(r)$ Development of foul smell on treatment with chloroform and alcoholic $\mathrm{KOH}$ |
| $(D)$ $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{NH}_2$ | $(s)$ Reduction with diisobutylaluminium hydride $(DIBAL-H)$ |
| $(t)$ Alkaline hydrolysis |

$(a)\,N{H_4}N{O_2}\xrightarrow{\Delta }{N_2} + {H_2}O$
$(b)\,N{H_4}N{O_3}\xrightarrow{\Delta }{N_2}O + {H_2}O$
$(c)\,N{a_2}C{O_3}\xrightarrow{\Delta }N{a_2}O + C{O_2}$
$(d)\,N{H_4}Cl\xrightarrow{\Delta }N{H_3} + HCl$