MCQ
In alkyl cyanide alkyl group attached with
- ✓$C$ of $CN$ group
- B$N$ of $CN$ group
- CEither $C$ or $N$ of $CN$ group
- DBoth $C$ and $N$ of $CN$ group
$\therefore$ In alkyl cyanide, alkyl group is attached to $C$ of $CN$.
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Reason : The higher oxidation states for the group $14$ elements are more stable for the heavier members of the group due to ‘inert pair effect’.
| Experiment | $\frac{[ X ]}{ mol \;L ^{-1}}$ | $\frac{[ Y ]}{ mol\; L ^{-1}}$ | $\frac{\text { Initial rate }}{ mol\; L ^{-1}\; min ^{-1}}$ |
| $I$ | $0.1$ | $0.1$ | $2 \times 10^{-3}$ |
| $II$ | $0.2$ | $0.2$ | $4 \times 10^{-3}$ |
| $III$ | $0.4$ | $0.4$ | $M \times 10^{-3}$ |
| $IV$ | $0.1$ | $0.2$ | $2 \times 10^{-3}$ |
Examine the data of table and calculate ratio of numerical value of $M$
when $\underset{(i)}{\mathop{\gamma =C{{H}_{3}}CO_{2}^{-},}}\,\,\,\,\,\,\underset{(ii)}{\mathop{Cl-C{{H}_{2}}-CO_{2}^{-},}}\,\,\,\,\,\,\,\underset{(iii)}{\mathop{Ph-SO_{3}^{-}}}\,$