$Ksp$ of $AgCl = 1.2 \times 10^{-10}$,
$Ksp$ of $AgI = 1.7 \times 10^{-16}$
$Ksp$ of $AgSCN = 7.1 \times 10^{-7}$,
$Ksp$ of $AgBr = 3.5 \times10^{-13}$
- ✓$I^-$
- B$Cl^-$
- C$Br^-$
- D$SCN^-$
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$\left[\right.$ Use $: \mathrm{H}^{+}(\mathrm{aq})+\mathrm{OH}^{-}(\mathrm{aq}) \rightarrow \mathrm{H}_{2} \mathrm{O}: \Delta_{\mathrm{\gamma}} \mathrm{H}=-57.1\, \mathrm{k} \mathrm{J} \,\mathrm{mol}^{-1}$
Specific heat of $\mathrm{H}_{2} \mathrm{O}=4.18 \mathrm{Jk}^{-} \mathrm{g}^{-}$
density of $\mathrm{H}_{2} \mathrm{O}=1.0\, \mathrm{~g} \mathrm{~cm}^{-3}$
Assume no change in volume of solution on mixing.]
Assertion ($A$): Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always $-57 \mathrm{~kJ} \mathrm{~mol}^{-1}$
Reason ($R$): Enthalpy of neutralisation is the amount of heat liberated when one mole of $\mathrm{H}^{+}$ions furnished by acid combine with one mole of ${ }^{-} \mathrm{OH}$ ions furnished by base to form one mole of water. In the light of the above statements, choose the correct answer from the options given below.