MCQ
In Brown ring $[Fe(H_2O)_5NO]SO_4$ primary valency of $Fe$ is
  • $+1$
  • B
    $+2$
  • C
    $+3$
  • D
    $+6$

Answer

Correct option: A.
$+1$
a
NO in brown ring complex has $+1$ oxidation state.

Let oxidation state of $Fe$ be $x$.

Since the overall charge on the coordination sphere, $\left[ Fe \left( H _2 O \right)_5 NO ^{+}\right]$is $+2$, the sum of oxidation states of all elements in it should be equal to $+2$.

Therefore, $x +1=+2$

or, $x =+1$

Hence, the oxidation state of iron in the brown ring complex is $+1$.

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