MCQ
In Dumas' process, when nitrogen is estimated in any organic compound, the last gas collected is :
- ✓$N _2$
- BNO
- C$NH _3$
- D$N _2 O _4$
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Given : $\Delta H _{ f }^{\ominus}\left( Al _2 O _3\right)=-1700\,kJ\,mol ^{-1}$
$\Delta H _{ f }^\theta\left( Fe _2 O _3\right)=-840\,kJ\,mol ^{-1}$
Molar mass of $Fe , Al$ and $O$ are $56,27$ and $16\,g\,mol ^{-1}$ respectively.

$CH \equiv CH\xrightarrow[{(excess)}]{{NaN{H_2}/liq.N{H_3}}}A\xrightarrow{{2C{H_3} - I}}B\xrightarrow[{quinolene}]{{{H_2}/Pd - BaS{O_4}}}C$
$C\xrightarrow[{quinolene}]{{{H_2}/Pd - BaS{O_4}}}\xrightarrow[{liq.\,N{H_3}}]{{NaN{H_2}}}D$