MCQ
In given reactions which one is correct ?
  • A
    $\begin{array}{*{20}{c}}
      {\begin{array}{*{20}{c}}
      {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}} \\ 
      {\,\,\,\,\,\,\,\,|} 
    \end{array}} \\ 
      {C{H_2} = CH - C - COOH} \\ 
      {\,\,\,\,\,\,\,\,\,\,|} \\ 
      {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_3}} 
    \end{array}$  $\xrightarrow{{NaOH\, + \,CaO\,/\,\Delta }}$ $\begin{array}{*{20}{c}}
      {C{H_2} = CH - CH - C{H_3}} \\ 
      {\,\,\,\,\,\,\,\,\,\,|} \\ 
      {\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,C{H_{3\,}}} 
    \end{array}$
  • B
    $\begin{array}{*{20}{c}}
      {\begin{array}{*{20}{c}}
      {\,\,\,\,\,\,\,\,\,\,\,COOH} \\ 
      {|\,\,\,\,\,} \\ 
      {H - C - C{H_3}} \\ 
      {|\,\,\,\,\,\,} 
    \end{array}} \\ 
      {H - C - C{H_3}} \\ 
      {|\,\,\,\,\,\,\,} \\ 
      {D\,\,\,\,\,\,} 
    \end{array}\,$ $\xrightarrow[{(ii)\,\,B{r_2}/CC{l_4}/\Delta }]{{(i)\,\,A{g_2}O}}$ $\begin{array}{*{20}{c}}
      {\begin{array}{*{20}{c}}
      {Br} \\ 
      {|\,\,\,\,\,} \\ 
      {H - C - C{H_3}} \\ 
      {|\,\,\,\,\,} 
    \end{array}} \\ 
      {H - C - C{H_3}} \\ 
      {|\,\,\,\,\,\,} \\ 
      {D\,\,\,\,} 
    \end{array}$ + Enantiomer
  • C
    $\begin{array}{*{20}{c}}
      {C{H_3} - CH - C{H_2} - N{O_2}\xrightarrow[\Delta ]{{O{H^ - }/{H_2}O}}C{H_2} = CH - C{H_2} - N{O_2}} \\ 
      {\,\,\,\,\,\,|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\ 
      {\,\,F\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} 
    \end{array}$

Answer

Correct option: D.

d
Internal cannizzaro reaction then esterification

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