In the reaction * 20 c * 20 c C H_2 OH | , , , , , , , , , , , , , , , , , , CHOH , , , | , , , , , , , , , , , , , , , , , C H_2 OH + * 20 c COOH | , , , , , , , , , , , , , , , , COOH 110 , ,^o C ,(A) product (A) will be

In the reaction * 20 c * 20 c C H_2 OH | , , , , , , , , , , , , …

MCQ

In the reaction $\begin{array}{*{20}{c}}
{\begin{array}{*{20}{c}}
{C{H_2}OH} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,}
\end{array}} \\
{CHOH\,\,\,} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{C{H_2}OH}
\end{array}$ $+$ $\begin{array}{*{20}{c}}
{COOH} \\
{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,} \\
{COOH}
\end{array}$ $\xrightarrow{{110\,{\,^o}C}}\,(A)$ product $(A)$ will be

✓
Glycerol monoformate
B
Allyl alcohol
C
Formaldehyde
D
Acetic acid

✓

Answer

Correct option: A.

Glycerol monoformate

a
$\underset{Glycerol}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,C{{H}_{2}}OH \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
CHOH \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{2}}OH \\
\end{matrix}}}\,$ $+$ $\underset{Oxalic\,acid}{\mathop{\begin{matrix}
COOH \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
COOH \\
\end{matrix}}}\,$$\xrightarrow{{110\,{\,^o}C}}$ $\underset{Glycerol\,\,acid\,\,oxalate}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,O \\
\,\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,|| \\
C{{H}_{2}}-O-C-C-OH\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
CHOH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{2}}OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}}}\,$ $\xrightarrow{-\,C{{O}_{2}}}$ $\underset{Glycerol\,\,monoformate}{\mathop{\begin{matrix}
\begin{matrix}
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,O\,\,\,\,\,\,\,\,\,\, \\
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,||\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{2}}-O-C-OH\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix} \\
CHOH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{2}}OH\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
\end{matrix}}}\,$

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