MCQ
Incorrect statement regarding $BF_2NH_2$ molecule is
- A$FBF$ bond angle $< 120^o$
- B$HNH$ bond angle $> 109^o28'$
- CExlubits intermolecular $H-$ bond
- ✓Hybridization of $N-$ atom is $sp^3$
$*\, FBF$ bond angle $< 120^o$ ($VSPER$ theory)
$* \,H N H$ bond angle is less than $120^o$ but greater than $109^o28$' due to back bonding.
$*$ Due to presence of $H-$ atom attached to nitrogen this molecule can exhibits intermolecular $H-$ bonding.
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Which of the following product $(s)$ is/are can be obtained in the above reaction.
(image)
($A$) $R$ is steam volatile
($B$) $Q$ gives dark violet coloration with $1 \%$ aqueous $FeCl_3$ solution
($C$) $S$ gives yellow precipitate with $2, 4$-dinitrophenylhydrazine
($D$) $S$ gives dark violet coloration with $1 \%$ aqueous $FeCl_3$ solution
| Condition | Temperature |
| $(1)$ Spontaneous | $(p)$ $273\,K$ |
| $(2)$ At equilibrium | $(q)$ $260\, K$ |
| $(3)$ Non-spontaneous | $(r)$ $280\, K$ |