- A$Si$
- ✓$Pb$
- C$Ge$
- D$Sn$
This is most stated in Groups 13,14 and 15
A possible given explanation is that due to presence of f-subshell electrons are to diffused, due to the shape of the forbitals, to effectively shield the s electrons from the pull of the nucleus.
A good example would be the elements of Group $13 .$ Aluminium in +1 state is unknown, and the stability of +1 oxidation state increases as we go down the group.
Thallium is most stable in +1 oxidation state, and compounds of Thallium in +3 oxidation state are known to be very strong oxidising agents, and have a tendency to reduce quickly to +1 state.
Hence option B is correct.
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| $t/s$ | $0$ | $30$ | $60$ | $90$ |
| $ Ester/$ $mol\,L^{-1}$ | $0.55$ | $0.31$ | $0.17$ | $0.085$ |
What will be the average rate of reaction between the time interval $30$ to $60\, seconds$ ?
$[\Lambda_{\mathrm{H}^{+}}^{\circ}=350 \,\mathrm{~S}\, \mathrm{~cm}^{2}\, \mathrm{~mol}^{-1},\Lambda_{\mathrm{CH}_{3} \mathrm{COO}^{-}}^{\circ}=50\, \mathrm{~S}\, \mathrm{~cm}^{2}\, \mathrm{~mol}^{-1}]$
