MCQ
Lanthanoid contraction is caused due to
  • A
    the same effective nuclear charge from $Ce$ to $Lu$
  • the imperfect shielding on outer electrons by $4f$ electrons from the nuclear charge
  • C
    the appreciable shielding on outer electrons by $4f$ electrons from the nuclear charge
  • D
    the appreciable shielding on outer electrons by $5d$ electrons from the nuclear charge

Answer

Correct option: B.
the imperfect shielding on outer electrons by $4f$ electrons from the nuclear charge
b
The main reason of lanthanide contraction is, poor shielding of $4f$ electrons on the outer most shell electrons. As $f$ orbital is defused nature so shielding of $4$f electron is imperfect that is why nucleus can attract outer most shell electron easily and the size of atom decreases.

In lanthanides, there is poorer shielding of $5 d$ electrons by $4f$ electrons resulting in greater attraction of the nucleus over $5d$ electrons and reduction of the atomic radii.

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