Question
Lower aliphatic carboxylic acids are miscible with water while higher carboxylic acids are immiscible.

Answer

(1) Lower aliphatic carboxylic acids are miscible with water due to the formation of hydrogen bonding with water molecules.
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(2) Hydrogen bonding between acid and water. As the molecular mass increases (he solubility of carboxylic acids in water decreases. The insolubility of carboxylic acids is due to increased hydrophobic interaction of hydrocarbon parts with water.

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