MCQ
(major) Product $(A)$ is


- A

- B

- ✓

- D







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| Rate constant | Activation energy | |
| Step $1$ | $k_1$ | $E_{a_1} = 180\,kJ /mol$ |
| Step $2$ | $k_2$ | $E_{a_2} = 80\,kJ /mol$ |
| Step $3$ | $k_3$ | $E_{a_3} = 50\,kJ /mol$ |
overall rate constant, $k = {\left( {\frac{{{k_1}{k_2}}}{{{k_3}}}} \right)^{2/3}}$ overall activation energy of the reaction will be ........ $kJ\,mol$
$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$
rate law is $R = K\, [NO_2]' [O_3]'$.
Which of these possible reaction mechanisms is consistent with the rate law?
Mechanism $I :$
$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)
Mechanism $II :$
$O_3(g) \rightleftharpoons O_2(g) + [O]$ (fast)
$NO_2(g) + [O] \to NO_3$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5$ (fast)