Question
Mark the correct options:
  1. An atom with a vacancy has smaller energy that a neutral atom.
  2. K X-ray is emitted when a hole makes a jump from the K shell to some other shell.
  3. The wavelength of K X-ray is smaller than the wavelength of L X-ray of the same material.
  4. The wavelength of $\text{K}_\alpha$ X-ray is smaller than the wavelength of $\text{K}_\beta$ X-ray of the same material.

Answer

  1. K X-ray is emitted when a hole makes a jump from the K shell to some other shell.
  2. The wavelength of K X-ray is smaller than the wavelength of L X-ray of the same material.

Explanation:

Energy of a vacant atom is higher than that of a neutral atom.

Hence, option (a) is incorrect.

K X-ray is emitted when an electron makes a jump to the K shell from some other shell. As a result, a positive charge hole is created in the outer shell. As the electron continuously moves to the K shell, the hole moves from the K shell to some other shell.

Hence, option (b) is correct.

K X-ray is emitted due to the transition of an electron from the L or M shell to the K shell and L X-ray is emitted due to the transition of an electron from the M or N shell to the L shell. The energy involved in the transition from the L or M shell to the K shell is higher than the energy involved in the transition from the M or N shell to the L shell. Since the energy is inversely proportional to the wavelength, the wavelength of the K X-ray is smaller than the wavelength of the L X-ray of the same material. Hence, option (c) is correct.

If EK, EL and EM are the energies of K, L and M shells, respectively, then the wavelength of $\text{K}_\alpha$ X-ray $(\lambda_1)$ is given by

$\lambda_1=\frac{\text{hc}}{\text{E}_\text{K}-\text{E}_\text{L}}$

Here,

h = Planck's constant

c = Speed of light

Wavelength of the $\text{K}_\beta$ x-ray $(\lambda_2)$ is given by

$\lambda_2=\frac{\text{hc}}{\text{E}_\text{K}-\text{E}_\text{M}}$

As the difference of energies (EK - EM) is more than (E- EL), $\lambda_2$ is less than $\lambda_1$.

Hence, option (d) is not correct.

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