- AHydrogen
- BNitrogen
- COxygen
- DNone of the above
Explanation:
Acidulated water is a mixture of cold water and small amount if vinegar, lemon juice or lime juice. it's just used as a soak to prevent discoloration of some fruits and vegetables that darken quikly when their cut surfaces are exposed to air. During electrolysis of acidulated water, hydrogen gas (H2) is liberated at cathode.
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$2MnO_4^-+ 10I^-+ 16H^+ \to 2Mn^{2+} + 5I_2 + 8 H_2O$
The rate of apperance of $I_2$ is
(Given $\ln 10=2.3, R =8.3 JK ^{-1} mol ^{-1}, \log 2=0.30$ )
$ \mathrm{Ag}^{+}+\mathrm{e}^{-} \rightarrow \mathrm{Ag} ; \mathrm{E}_{\text {red }}^{\circ}=0.8 \mathrm{~V} $
$ \mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow \text { Gluconic acid }\left(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_7\right)+2 \mathrm{H}^{+}+2 \mathrm{e}^{-} ; \mathrm{E}_{\text {oxd }}^{\circ}=-0.05 \mathrm{~V} $
$ \mathrm{Ag}\left(\mathrm{NH}_3\right)_2^{+}+\mathrm{e}^{-} \rightarrow \mathrm{Ag}(\mathrm{s})+2 \mathrm{NH}_3 ; \mathrm{E}_{\text {red }}^{\circ}=0.337 \mathrm{~V}$
[Use $2.303 \times \frac{\mathrm{RT}}{\mathrm{F}}=0.0592$ and $\frac{\mathrm{F}}{\mathrm{RT}}=38.92$ at $298 \mathrm{~K}$ ]
$1.$ $2 \mathrm{Ag}^{+}+\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6+\mathrm{H}_2 \mathrm{O} \rightarrow 2 \mathrm{Ag}(\mathrm{s})+\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_7+2 \mathrm{H}^{+}$
Find $\ln \mathrm{K}$ of this reaction.
$(A)$ $66.13$ $(B)$ $58.38$ $(C)$ $28.30$ $(D)$ $46.29$
$2.$ When ammonia is added to the solution, $\mathrm{pH}$ is raised to $11$ . Which half-cell reaction is affected by $\mathrm{pH}$ and by how much?
(A) $E_{\text {oxd }}$ will increase by a factor of $0.65$ from $E_{\text {oxd }}^{\circ}$
(B) $E_{\text {oxd }}$ will decrease by a factor of $0.65$ from $E_{\mathrm{cod}}^{\prime}$
(C) $\mathrm{E}_{\text {red }}$ will increase by a factor of $0.65$ from $\mathrm{E}_{\text {rod }}^{\circ}$
(D) $E_{\text {red }}$ will decrease by a factor of $0.65$ from $E_{\text {rod }}^2$
$3.$ Ammonia is always is added in this reaction. Which of the following must be incorrect?
$(A)$ $\mathrm{NH}_3$ combines with $\mathrm{Ag}^{+}$to form a complex.
$(B)$ $\mathrm{Ag}\left(\mathrm{NH}_3\right)_2^{+}$is a stronger oxidising reagent than $\mathrm{Ag}^{+}$.
$(C)$ In absence of $\mathrm{NH}_3$ silver salt of gluconic acid is formed.
$(D)$ $\mathrm{NH}_3$ has affected the standard reduction potential of glucose/gluconic acid electrode.
Give the answer question $1,2$ and $3.$