MCQ
Nitrogen $(I)$ oxide is produced by
- Athermal decomposition of sodium nitrite at low temperature
- Bthermal decomposition of ammonium nitrite
- Cdisproportionation of $N_2O_4$
- ✓interaction of hydroxyl amine and nitrous acid
✓
Answer
Correct option: D.
interaction of hydroxyl amine and nitrous acid
d
Reaction is: $NH _2 OH + HNO _2 \rightarrow N _2 O +2 H _2 O$
Reaction is: $NH _2 OH + HNO _2 \rightarrow N _2 O +2 H _2 O$
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Major product for the reaction is :
$\begin{matrix}
ONa\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C=C{{H}_{2}}\xrightarrow{HC\equiv CH}\xrightarrow{{{H}^{+}}}\xrightarrow[Pd-BaS{{O}_{4}}]{{{H}_{2}}}\xrightarrow[\Delta ]{A{{l}_{2}}{{O}_{3}}} \\
\end{matrix}$
→ONa\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\, \\
C{{H}_{3}}-C=C{{H}_{2}}\xrightarrow{HC\equiv CH}\xrightarrow{{{H}^{+}}}\xrightarrow[Pd-BaS{{O}_{4}}]{{{H}_{2}}}\xrightarrow[\Delta ]{A{{l}_{2}}{{O}_{3}}} \\
\end{matrix}$
End product of the reaction is