MCQ
Of the following which is diamagnetic in nature ?
  • A
    $[CoF_6]^{3+}$
  • B
    $[NiCl_4]^{2-}$
  • C
    $[CuCl_4]^{2-}$
  • $[Ni(CN)_4]^{2-}$

Answer

Correct option: D.
$[Ni(CN)_4]^{2-}$
d
$\left[ Ni ( CN )_4\right]^{2+}$ has $d ^8( Ni , 2+)$ which undergoes pairing to give (refer to image) $dsp ^2$ hybridisation and no unpaired electron so diamagnetic.

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