MCQ
On this transformation $PCl_5 \to PCl_6^-$ what changes will take place :-
- AHybridisation of $'P'$ will change
- BMolecular geometry changes
- CShape of molecule changes
- ✓All of the above
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(Molecular mass of $CHCl_3 = 119.5 \,u$ and molecular mass of $CH_2Cl_2 = 85\, u$)
$\underset{A}{\mathop{PhF}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\underset{B}{\mathop{PhCl}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\underset{C}{\mathop{PhBr}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\underset{D}{\mathop{PhI}}\,$
$(I)\,\, AgNO_3$
$(II)\,\, CaCO_3$
$(III) \,\,Pb(NO_3)_2$
$(IV) \,\,Na_2CO_3$
Step$-1$ : ${\text{A + E }} \rightleftharpoons AE$ (fast)
Step$-2$ :${\text{AE + A }} \to {A_2} + E$ (slow)
Step$-3$ :${{\text{A}}_2}{\text{ + B }} \to {\text{D}}$ (fast)
what rate law best agrees with this mechanism