MCQ
Order of decreasing basic strengths of halides is
- A$F^- > Cl^- > I^- > Br^-$
- ✓$F^- > Cl^- > Br^- > I^-$
- C$I^- > Br^- > Cl^- > F^-$
- D$I^- > Cl^- > Br^- > F^-$
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$\left( A \right)\xrightarrow{{\operatorname{Re}duction}}\left( B \right)\xrightarrow{{HN{O_2}}}{C_2}{H_5}OH$
$(i)\,\,(CH_3)_2CH - CH_2Br \xrightarrow{{{C_2}{H_5}OH}}$ $ (CH_3)_2CH - CH_2OC_2H_5 + HBr$
$(ii)\,\,(CH_3)_2CH - CH_2Br \xrightarrow{{{C_2}{H_5}O^-}} $ $(CH_3)_2CH - CH_2OC_2H_5 + Br^-$
The mechanisms of reactions $(i)$ and $(ii)$ are respectively