MCQ
Oxidation number of As in ${H_2}AsO_4^ - $ is
- A$6$
- B$7$
- ✓$5$
- D$9$
$2 + x - 8 = - 1$
$x - 6 = - 1$
$x = 5$
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What is $A$
$Cl_2(aq)+H_2SO_4(aq) \rightarrow S(s)+2H^+(aq)+2Cl^-$
The rate equation for this reaction is
rate $=k[Cl_2][H_2S]$
Which of these mechanisms is/are consistent with this rate equation ?
$A.\,\, Cl_2 + H_2S \rightarrow H^+ + Cl^- + Cl^+ + HS^-\,\, (slow)$
$Cl^+ +HS^- \rightarrow H^+ +Cl^- +S \,(fast)$
$B.\,\, H_2S \rightleftharpoons H^+ + HS^-\,$ (fast equilibrium)
$Cl_2^+ + HS^- \rightarrow 2CI^- + H^+ + S\,\, (Slow)$
