$p$-Amino- $N, N$-dimethylaniline is added to a strongly acidic solution of ${X}$. The resulting solution is treated with a few drops of aqueous solution of ${Y}$ to yield blue coloration due to the formation of methylene blue. Treatment of the aqueous solution of ${Y}$ with the reagent potassium hexacyanoferrate$(II)$ leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of ${Y}$ with the solution of potassium hexacyanoferrate$(III)$ leads to a brown coloration due to the formation of ${Z}$.

$1.$ The compound ${X}$ is

$(A)$ $\mathrm{NaNO}_3$ $(B)$ $\mathrm{NaCl}$ $(C)$ $\mathrm{Na}_2 \mathrm{SO}_4$ $(D)$ $\mathrm{Na}_2 \mathrm{~S}$

$2.$ The compound ${Y}$ is

$(A)$ $\mathrm{MgCl}_2$ $(B)$ $\mathrm{FeCl}_2$ $(C)$ $\mathrm{FeCl}_3$ $(D)$ $\mathrm{ZnCl}_2$

$3.$ The compound ${Z}$ is

$(A)$ $\left.\mathrm{Mg}_2 \mid \mathrm{Fe}(\mathrm{CN})_6\right]$ $(B)$ $\operatorname{Fe}\left[\mathrm{Fe}(\mathrm{CN})_6\right]$

$(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(D)$ $\mathrm{K}_2 \mathrm{Zn}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$

Give the answer question $1,2$ and $3.$

Q: $p$-Amino- $N, N$-dimethylaniline is added to a strongly acidic solution of ${X}$. The resulting solution is treated with a few drops of aqueous solution of ${Y}$ to yield blue coloration due to the formation of methylene blue. Treatment of the aqueous solution of ${Y}$ with the reagent potassium hexacyanoferrate$(II)$ leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of ${Y}$ with the solution of potassium hexacyanoferrate$(III)$ leads to a brown coloration due to the formation of ${Z}$. $1.$ The compound ${X}$ is $(A)$ $\mathrm{NaNO}_3$ $(B)$ $\mathrm{NaCl}$ $(C)$ $\mathrm{Na}_2 \mathrm{SO}_4$ $(D)$ $\mathrm{Na}_2 \mathrm{~S}$ $2.$ The compound ${Y}$ is $(A)$ $\mathrm{MgCl}_2$ $(B)$ $\mathrm{FeCl}_2$ $(C)$ $\mathrm{FeCl}_3$ $(D)$ $\mathrm{ZnCl}_2$ $3.$ The compound ${Z}$ is $(A)$ $\left.\mathrm{Mg}_2 \mid \mathrm{Fe}(\mathrm{CN})_6\right]$ $(B)$ $\operatorname{Fe}\left[\mathrm{Fe}(\mathrm{CN})_6\right]$ $(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(D)$ $\mathrm{K}_2 \mathrm{Zn}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$ Give the answer question $1,2$ and $3.$

a $1.$ $\underset{(X)}{N a_2} S +2 H ^{+} \rightarrow H _2 S +2 Na a^{+}$ $Image$ $4 F e C l_3+3 K_4\left[{ }^{I I} e(C N)_6\right] \rightarrow F e_4\left[F e(C N)_6\right]_3+2 KCl$ Intence blue $FeCl _3+ K _3\left[ Fe ( CN )_6\right] \rightarrow Fe \left[ Fe ( CN )_6\right]+3 KCl$ Brown coloration $(Y)-F e C l_3$

Question

$p$-Amino- $N, N$-dimethylaniline is added to a strongly acidic solution of ${X}$. The resulting solution is treated with a few drops of aqueous solution of ${Y}$ to yield blue coloration due to the formation of methylene blue. Treatment of the aqueous solution of ${Y}$ with the reagent potassium hexacyanoferrate$(II)$ leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of ${Y}$ with the solution of potassium hexacyanoferrate$(III)$ leads to a brown coloration due to the formation of ${Z}$.

$1.$ The compound ${X}$ is

$(A)$ $\mathrm{NaNO}_3$ $(B)$ $\mathrm{NaCl}$ $(C)$ $\mathrm{Na}_2 \mathrm{SO}_4$ $(D)$ $\mathrm{Na}_2 \mathrm{~S}$

$2.$ The compound ${Y}$ is

$(A)$ $\mathrm{MgCl}_2$ $(B)$ $\mathrm{FeCl}_2$ $(C)$ $\mathrm{FeCl}_3$ $(D)$ $\mathrm{ZnCl}_2$

$3.$ The compound ${Z}$ is

$(A)$ $\left.\mathrm{Mg}_2 \mid \mathrm{Fe}(\mathrm{CN})_6\right]$ $(B)$ $\operatorname{Fe}\left[\mathrm{Fe}(\mathrm{CN})_6\right]$

$(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(D)$ $\mathrm{K}_2 \mathrm{Zn}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$

Give the answer question $1,2$ and $3.$

A$(D,C,B)$
B$(D,B,A)$
C$(A,C,D)$
D$(A,C,C)$

IIT 2009, Difficult

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