MCQ
Phenol on reaction with dilute nitric acid, gives two products. Which method will be most effective for large scale separation ?
  • A
    Chromatographic separation
  • B
    Fractional Crystallisation
  • Steam distillation
  • D
    Sublimation

Answer

Correct option: C.
Steam distillation
c
Para product has higher boiling point than ortho as intermolecular $H$-bond is possible in former, where as intramolecular $H$-bond is possible in ortho product.

Steam distillation can separate them as ortho product is steam volatile.

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