- A$Br_2/CCl_4$
- BBaeyer's Reagent
- ✓$AgNO_3 + NH_4OH$
- D$O_3$
$C{H_3} - C \equiv CH\xrightarrow{{AgN{O_3} + N{H_4}OH}}\mathop {C{H_3} - C \equiv \bar C\,Ag}\limits_{white\,ppt} \downarrow $
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Statement $I$: Aqueous solution of $K _2 Cr _2 O$, is preferred as a primary standard in volumetric analysis over $Na _2 Cr _2 O$, aqueous solution
Statement $II:$ $K _2 Cr _2 O$, has a higher solubility in water than $Na _2 Cr _2 O _7$
In the light of the above statements, choose the correct answer from the options given below:
$S\left( s \right) + {O_2}\left( g \right) \rightleftharpoons S{O_2}\left( g \right);{K_1} = {10^{52}}$
$2S\left( s \right) + 3{O_2}\left( g \right) \rightleftharpoons 2S{O_3}\left( g \right);{K_2} = {10^{129}}$
The equilibrium constant for the reaction $2S{O_2}\left( g \right) + {O_2}\left( g \right) \rightleftharpoons 2S{O_3}\left( g \right)$ is