Question
Read the passage given below and answer the following questions:
A tertiary alcohol H upon acid catalysed dehydration gives a product I. Ozonolysis of I leads to compounds J and K. Compound J upon reaction with KOH gives benzyl alcohol and a compound I, whereas K on reaction with KOH gives only M.
The following questions are multiple choice questions. Choose the most appropriate answer:
- Compound H is formed by the reaction of:
- The structure of compound I is:
- The structures of compound J, K and I, respectively, are:
- $\mathrm{PhCOCH}_3, \mathrm{PhCH}_2 \mathrm{COCH}_3$ and $\mathrm{PhCH}_2 \mathrm{COO}^{-} \mathrm{K}^{+}$
- $\mathrm{PhCHO}, \mathrm{PhCH}_2 \mathrm{CHO}$ and $\mathrm{PhCOO}^{-} \mathrm{K}^{+}$
- $\mathrm{PhCOCH}_3, \mathrm{PhCH}_2 \mathrm{CHO}$ and $\mathrm{CH}_3 \mathrm{COO}^{-} \mathrm{K}^{+}$
- $\mathrm{PhCHO}, \mathrm{PhCOCH}_3$ and $\mathrm{PhCOO}^{-} \mathrm{K}^{+}$
- When (J) is treated with acetic anhydride, in the presence of corresponding salt of an acid, the product obtained is:
- Cinnamic acid.
- Crotonic acid.
- Maleic acid.
- Benzylic acid.
- Which of the following statements is correct for compound (K)?
- It reacts with alkaline KMn04 followed by acidic hydrolysis and forms benzoic acid.
- It reacts with iodine and NaOH to form triiodomethane.
- It is prepared by the reaction of benzene with benzoyl chloride in presence of anhydrous aluminium chloride.
- It reacts with freshly prepared ammoniacal silver nitrate solution.

