Question

Read the passage given below and answer the following questions:
A tertiary alcohol H upon acid catalysed dehydration gives a product I. Ozonolysis of I leads to compounds J and K. Compound J upon reaction with KOH gives benzyl alcohol and a compound I, whereas K on reaction with KOH gives only M.

The following questions are multiple choice questions. Choose the most appropriate answer:
  1. Compound H is formed by the reaction of:
  1. The structure of compound I is:
  1. The structures of compound J, K and I, respectively, are:
  1. $\mathrm{PhCOCH}_3, \mathrm{PhCH}_2 \mathrm{COCH}_3$ and $\mathrm{PhCH}_2 \mathrm{COO}^{-} \mathrm{K}^{+}$
  2. $\mathrm{PhCHO}, \mathrm{PhCH}_2 \mathrm{CHO}$ and $\mathrm{PhCOO}^{-} \mathrm{K}^{+}$
  3. $\mathrm{PhCOCH}_3, \mathrm{PhCH}_2 \mathrm{CHO}$ and $\mathrm{CH}_3 \mathrm{COO}^{-} \mathrm{K}^{+}$
  4. $\mathrm{PhCHO}, \mathrm{PhCOCH}_3$ and $\mathrm{PhCOO}^{-} \mathrm{K}^{+}$
  1. When (J) is treated with acetic anhydride, in the presence of corresponding salt of an acid, the product obtained is:
  1. Cinnamic acid.
  2. Crotonic acid.
  3. Maleic acid.
  4. Benzylic acid.
  1. Which of the following statements is correct for compound (K)?
  1. It reacts with alkaline KMn04 followed by acidic hydrolysis and forms benzoic acid.
  2. It reacts with iodine and NaOH to form triiodomethane.
  3. It is prepared by the reaction of benzene with benzoyl chloride in presence of anhydrous aluminium chloride.
  4. It reacts with freshly prepared ammoniacal silver nitrate solution.

Answer

  1. (b)

Explanation:
  1. (a)

Explanation:
  1. (d) $\mathrm{PhCHO}, \mathrm{PhCOCH}_3$ and $\mathrm{PhCOO}^{-} \mathrm{K}^{+}$
Explanation:
  1. (a) Cinnamic acid.
Explanation:
$\text{C}_6\text{H}_5\text{CHO}+\text{(CH}_2\text{CO)}_2\text{O}\xrightarrow[\text{-CH}_3\text{COOH}]{\text{CH}_3\text{COONa}} \ \ \ \ \ \ \ \ \\\text{Benzaldehyde Acetic anhydride}$
$\text{C}_6\text{H}_5-\text{CH}=\text{CH}-\text{COOH} \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \\ \ \ \ \ \ \ \ \ \ \ \ \ \text{Cinnarnlc add }$
  1. (b) It reacts with iodine and NaOH to form triiodomethane.

Need a full question paper?

Generate a complete, print-ready paper with questions like this in minutes — across 16+ boards, with answer keys.

Start Generating Free

Similar questions

Note: In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Transparent soaps are made by dissolving soaps in ethanol.
Reason: Ethanol makes things invisible.
Note: In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Nitration of chlorobenzene leads to the formation of $m-$nitrochlorobenzene
Reason: $—NO_2$ group is a $m-$directing group.
In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Zinc becomes dull in moist air.
Reason: Zinc is coated by a thin film of its basic carbonate in moist air.
Note: In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Artificial sweeteners are added to the food to control the intake of calories.
Reason: Most of the artificial sweeteners are inert and do not metabolise in the body.
In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Sodium chloride used to clear snow on the roads.
Reason: Sodium chloride depresses the freezing point of water.
In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion : On increasing dilution, the specific conductance keep on increasing.
Reason : On increasing dilution, degree of ionisation of weak electrolyte increases and molality of ions also
increases.
In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Carbon$-$halogen bond in aryl halide has partial double bond character.
Reason: Aryl halides undergo nucleophilic substitution easily.
In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: bee and hep has same packing efficiency
Reason: bee arrangement has $2$ atoms per unit cell, while fee has $4$ atoms per unit cell.
In these questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion: Vinyl chloride is less reactive than alkyl chloride.
Reason: Stability of alkyl halide decreases as the strength of $C - X$ bond decreases.
Assertion (A): Boiling point of alkyl halides increases with an increase in molecular weight.
Reason (R): Boiling point of alkyl halides is in the order RI > RB > RCI > RF.