- ✓$SO_2$ is evolved
- BLead sulphate is produced at both electrodes
- CSulphuric acid is consumed
- DWater is formed
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The molar mass difference between compounds $Q$ and $R$ is $474 \mathrm{~mol}^{-1}$ and between compounds $P$ and $S$ is $172.5 \mathrm{~g} \mathrm{~mol}^{-1}$.
($1$)The number of heteroatoms present in one molecule of $R$ is. . . . . .
[Use: Molar mass (in g mol ${ }^{-1}$ ): $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$
Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]
($2$)The total number of carbon atoms and heteroatoms present in one molecule of $S$. . . . . .
[Use: Molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ ]: $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$
Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms
Give the answer quetion ($1$) and ($2$)
| List-$I$ | List-$II$ | ||
| $A$ | $[Fe(H_2O)_6]^{2+}$ | $P$ | $0$ |
| $B$ | $[Fe(H_2O)_6]^{3+}$ | $Q$ | $1$ |
| $C$ | $[Fe(CN)_6]^{4-}$ | $R$ | $2$ |
| $D$ | $[Fe(CN)_6]^{3-}$ | $S$ | $4$ |
| $E$ | $[Ni(H_2O)_4]^{2+}$ | $T$ | $5$ |
$A$ $||$ $B$ $||$ $C$ $||$ $D$ $||$ $E$
$Ni^{2+} | Ni = -0.25\, V$ ;
$Cu^{2+} | Cu = 0.34\, V$
$Ag^+ | Ag = 0.80\, V$ ;
$Zn^{2+} | Zn = -0.76 \,V$
Which of the following reactions under standard condition will not take place in the specified direction