Question
Sulphur disappears when boiled with sodium sulphite. Why?

Answer

When sodium sulphite is heated with sulphur, we get sodium thiosulphate which is soluble in water that is why sulphur disappears.
$\text{Na}_2\text{SO}_3+\text{S}\xrightarrow{\ \ \text{Heat}\ \ }\text{Na}_2\text{S}_2\text{O}_3$

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