Question
Tarnished silver contains Ag2S. Can this tarnish be removed by placing tarnished silver ware in an aluminium pan containing an inert electrolytic solution such as NaCl? The standard electrode potential for half reaction:
$\text{Ag}_2\text{S(s) + 2e}^-\xrightarrow{\ \ \ \ \ \ \ }2\text{Ag(s) + S}^{2-}\text{is}-0.71\text{V}$
and for $\text{Al}^{3+}+3\text{e}^{-}\xrightarrow{ \ \ \ \ \ \ \ \ \ \ }2\text{Al(s) is}-1.66\text{V}$

Answer

cell for reaction of tarnished silver ware with aluminium pan is (-0.71V) - (-1.66V) i.e., + 095V
Tarnished silver ware, therefore, can be cleaned by placing it in an aluminium pan as E°cell is positive.

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