MCQ
The aqueous solution containing which one of the following ions will be colourless
- ✓$S{c^{3 + }}$
- B$F{e^{2 + }}$
- C$T{i^{3 + }}$
- D$M{n^{2 + }}$ (Atomic number $Sc = 21,\, Fe = 26, \,Ti = 22, \,Mn = 25)$
$S{c^{ + 3}} \to 1{s^2}2{s^2}2{p^6}3{s^2}3{p^6}$
Due to presence of paired electron it will be colourless.
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| Column $I$ | Column $II$ |
| $(A)$ $\mathrm{O}_2^{-} \rightarrow \mathrm{O}_2+\mathrm{O}_2{ }^{2-}$ | $(p)$ redox reaction |
| $(B)$ $\mathrm{CrO}_4{ }^{2-}+\mathrm{H}^{+} \rightarrow$ | $(q)$ one of the products has trigonal planar structure |
| $(C)$ $\mathrm{MnO}_4^{-}+\mathrm{NO}_2^{-}+\mathrm{H}^{+} \rightarrow$ | $(r)$ dimeric bridged tetrahedral metal ion |
| $(D)$ $\mathrm{NO}_3^{-}+\mathrm{H}_2 \mathrm{SO}_4+\mathrm{Fe}^{2+} \rightarrow$ | $(s)$ disproportionation |
Reason : In the presence of a more volatile liquid solute, only the solute will form the vapours and solvent will not.