
- Aan optically active compound having chiral centre
- Ban optically inactive compound
- Ca meso compound
- ✓an optically active compound without having chiral centre


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Statement $(I)$ : Kjeldahl method is applicable to estimate nitrogen in pyridine.
Statement $(II)$ : The nitrogen present in pyridine can easily be converted into ammonium sulphate in Kjeldahl method.
In the light of the above statements, choose the correct answer from the options given below.
$3.0$ $moles$ of $\mathrm{PCl}_{5}$ is introduced in a $1\, \mathrm{~L}$ closed reaction vessel at $380\, \mathrm{~K}$. The number of moles of $\mathrm{PCl}_{5}$ at equilibrium is $.....\,\times 10^{-3}$. (Round off to the Nearest Integer)

$3 \mathrm{PbCl}_2+2\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \rightarrow \mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2+6 \mathrm{NH}_4 \mathrm{Cl}$
If $72 \mathrm{mmol}$ of $\mathrm{PbCl}_2$ is mixed with $50 \mathrm{mmol}$ of$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4$, then amount of $\mathrm{Pb}_3\left(\mathrm{PO}_4\right)_2$ formed is......... mmol. (nearest integer)