STD 11 - 9. Hydricarbon — JEE STD 11 Science — Question

$R - X \rightarrow R ^{\oplus} X ^{\ominus} \rightarrow R ^{\oplus} \| X ^{\ominus} \stackrel{ Y^\ominus }{\rightarrow} R - Y + X ^{\ominus}$

                     Ion pair       Solvent separated ion pair

A student writes general characteristics based on the given mechanism as:

$(a)$ The reaction is favoured by weak nucleophiles

$(b)$ $R^ \oplus$ would be easily formed if the substituents are bulky

$(c)$ The reaction is accompained by recemization

$(d)$ The reaction is favoured by non-polar solvents.

Which observations are correct $?$

${O_3}(g)\, + \,C{l^ * }(g)\, \to \,{O_2}(g) + Cl{O^ * }(g)$ ..... $(i)$               $[{K_i} = 5.2 \times {10^9}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$

$Cl{O^ * }(g) + {O^ * }(g)\, \to \,{O_2}(g) + \,C{l^ * }(g)$ ..... $(ii)$                $[{K_{ii}} = 2.6 \times {10^{10}}\,\,L\,mo{l^{ - 1}}\,{s^{ - 1}}]$

The closest rate constant for the overall reaction 

${O_3}(g){\mkern 1mu}  + {\mkern 1mu} {O^*}(g){\mkern 1mu}  \to {\mkern 1mu} 2{O_2}(g)$ is  ........... $L\,\,mo{l^{ - 1}}\,{s^{ - 1}}$

Given : Freezing point of $0.1\,M$ sucrose solution $= 272\,K$ and $F.pt.$ of water $= 273\,K$
Which of the following option show correct matches ? (assume, molarity=molality)

$'A'$ on reaction with sodium hypoiodite gives $'B',$ which on further heating with soda lime gives ' $C$ '. The compound ' $C$ ' is $....... .$