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$2NOCl\left( g \right) \rightleftharpoons 2NO\left( g \right) + C{l_2}\left( g \right)$
Given : $K_P = 8 \times 10^{12}\, atm$ at $500\, K$ use $R = 0.08\, L\, atm\, mol^{-1}\, K^{-1}$
$N{O_{\left( g \right)}} + \frac{1}{2}{O_2}_{\left( g \right)} \rightleftharpoons N{O_2}_{\left( g \right)}$
Given : $\Delta G^o_f (NO_2) = 52.0\, KJ/mole$
$\Delta G^o_f (NO) = 87.0\, KJ/mole$
$\Delta G^o_f (O_2) = 0\, KJ/mole$
$(I)$ ${P_4} + S{O_2}C{l_2} \to $
$(II)$ ${P_4} + SOC{l_2} \to $
$(III)$ $PC{l_5} + S{O_2} \to $
$(IV)$ $PC{l_5} + {C_2}{H_5}OH \to $
$(a) P_2O_7^{4-}$ $(b) S_2O_5^{2-}$
$(c) S_2O_7^{2-}$ $(d) Cl_2O_7$
$(e) Mn_2O_7$ $(f) S_2O_8^{2-}$
(Round of to the Nearest Integer).
(Given : $\left. R =8.314\, J\, mol ^{-1} K ^{-1}\right)$