The correct order of basicities of the following compounds is image mathop {C{H_3} - C{H_2} - N{H_2}}limits_{mathop 2limits } ,,mathop {{{(C{H_3})}_2}NH}limits_{mathop 3limits } mathop {C{H

Q: The correct order of basicities of the following compounds is image $\mathop {C{H_3} - C{H_2} - N{H_2}}\limits_{\mathop 2\limits } \,$$\,\mathop {{{(C{H_3})}_2}NH}\limits_{\mathop 3\limits } $ $\mathop {C{H_3} - \mathop {\mathop C\limits^{||} }\limits^O - N{H_2}}\limits_4 $

b (b) The relative basic charecter of ${1^o},{2^o}$ and ${3^o}$ amines also depends upon the nature of the alkyl group. $R$ Relative basic strength $ - C{H_3}$ ${R_2}NH > R - N{H_2} > {R_3}N > N{H_3}$ $ - {C_2}{H_5}$ ${R_2}NH > R - N{H_2} > N{H_3} > {R_3}N$ $ - CHM{e_2}$ $R - N{H_2} > N{H_3} > {R_2}NH > {R_3}N$ $ - CM{e_3}$ $N{H_3} > R - N{H_2} > {R_2}NH > {R_3}N$

SECTION - A [CHEMISTY - MCQ]

GSEB - English Medium

The correct order of basicities of the following compounds is

image

$\mathop {C{H_3} - C{H_2} - N{H_2}}\limits_{\mathop 2\limits } \,$$\,\mathop {{{(C{H_3})}_2}NH}\limits_{\mathop 3\limits } $

$\mathop {C{H_3} - \mathop {\mathop C\limits^{||} }\limits^O - N{H_2}}\limits_4 $

A$2 > 1 > 3 > 4$
B$1 > 3 > 2 > 4$
C$3 > 1 > 2 > 4$
D$1 > 2 > 3 > 4$

IIT 2001, Medium

STD 11 Science
JEE
STD 12 - 9. Amines
Chemistry

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$R$	Relative basic strength
$ - C{H_3}$	${R_2}NH > R - N{H_2} > {R_3}N > N{H_3}$
$ - {C_2}{H_5}$	${R_2}NH > R - N{H_2} > N{H_3} > {R_3}N$
$ - CHM{e_2}$	$R - N{H_2} > N{H_3} > {R_2}NH > {R_3}N$
$ - CM{e_3}$	$N{H_3} > R - N{H_2} > {R_2}NH > {R_3}N$

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