MCQ
The correct order of reactivity in electrophilic substitution reaction of the following compounds is :
  • A
    $\mathrm{B}>\mathrm{C}>\mathrm{A}>\mathrm{D}$
  • B
    $\mathrm{D}>\mathrm{C}>\mathrm{B}>\mathrm{A}$
  • C
     $\mathrm{A}>\mathrm{B}>\mathrm{C}>\mathrm{D}$
  • D
    $B>A>C>D$

Answer

$-\mathrm{CH}_3$ shows $+\mathrm{M}$ and $+\mathrm{I}$.

$-\mathrm{Cl}$ shows $+\mathrm{M}$ and $-\mathrm{I}$ but inductive effect dominates.

$-\mathrm{NO}_2$ shows $-\mathrm{M}$ and $-\mathrm{I}$.

Electrophilic substitution $\alpha \frac{1}{-\mathrm{M} \text { and }-\mathrm{I}}$

$\alpha+\mathrm{M} \text { and }+\mathrm{I}$

Hence, order is $\mathrm{B}>\mathrm{A}>\mathrm{C}>\mathrm{D}$.

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