MCQ
The electronic configuration of gadolinium (atomic no. $64$) is
  • A
    $[Xe]4{f^8}5{d^9}6{s^2}$
  • $[Xe]4{f^7}5{d^1}6{s^2}$
  • C
    $[Xe]4{f^3}5{d^5}6{s^2}$
  • D
    $[Xe]4{f^6}5{d^2}6{s^2}$

Answer

Correct option: B.
$[Xe]4{f^7}5{d^1}6{s^2}$
b
The electronic configuration of $L a\,(Z=57)$ is $[X e] \,5 d^1\, 6 s^2$

Therefore, further addition of electrons occurs in the lower energy $4 f$ - orbital till it is exactly half filled at $Eu \,(Z=63)$

Thus, the electronic configuration of $Eu$ is $[ Xe ] \,4 f ^7 \,6 s ^2$, thereafter, addition of next electron does not occur in the more stable exactly half filled $4 f^7$ shell but occurs in the little higher energy $5 d$ - orbital.

Thus, the electronic configuration of $Gd (Z=64)$ is $[X e]\, 4 f^7\, 5 d^1\, 6 s^2$

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