The Heisenberg’s uncertainty principle can be applied to :

$\begin{array}{|l|l|l|l|} \hline & Column\,I & & Column\,II \\ & (Reduction\,process) & & (Charge\,required) \\ \hline (a) & 1\,mol\,of\,MnO_4^-\,to\,Mn^{2+} & (p) & 193000\,\,C \\ \hline (b) & 1\,\,mole\,of\,Cr_2O_7^{2-}\,to\,Cr^{3+} & (q) & 289500\,\,C \\ \hline (c) & 1\,\,mole\,of\,Sn^{4+}\,to\,Sn^{2+} & (r) & 482500\,\,C \\ \hline (d) & 1\,mole\,of\,Al^{3+}\,to\,Al & (s) & 579000\,\,C \\ \hline \end{array}$

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The adduct of the compound $'A'$ obtained by the reaction with excess of isopropyl magnesium iodide, upon hydrolysis gives a tertiary alcohol. The compound $'A'$ is

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Which of the following represent correct order of hydration energy ?

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Assertion : Equivalent weight of a base $= \frac{Molecular\, weight}{Acidity}$
Reason : Acidity is the number of replaceable hydrogen atoms in one molecule of the base.

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${H_2}{O_{\left( g \right)}} + {C_{\left( s \right)}} \to C{O_{\left( g \right)}} + {H_2}\left( g \right)\,;\,\Delta H = 100\,kJ$

$C{O_{\left( g \right)}} + \frac{1}{2}{O_{2\left( g \right)}} \to C{O_{2\left( g \right)}}\,;\,\Delta H = - 300\,kJ$

${H_2}_{\left( g \right)} + \frac{1}{2}{O_2}_{\left( g \right)} \to {H_2}{O_{\left( g \right)}}\,;\,\Delta H = - 250\,kJ$

$C_{(s)} + O_{2(g)} \to CO_{2(g)} ; \Delta H = -x\, kJ$

The value of $x$ will be