The major product formed in the reaction is
  • A

  • B

  • C

  • D

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  • 1
    A trinitro compound, $1, 3,5$ tris-($4$-nitrophenyl) benzene, on complete reaction with an excess of $\mathrm{Sn} / \mathrm{HCl}$ gives major product, which on treatment with an excess of $NaNO_2 /  HCl$ at $0^{\circ} C$ provides $P$ as the product. $P$, upon treatment with excess of $H_2 O$ at room temperature, gives the product $Q$. Bromination of $Q$ in aqueous medium furnishes the product $R$. The compound $P$ upon treatment with an excess of phenol under basic conditions gives the product $S$.

    The molar mass difference between compounds $Q$ and $R$ is $474 \mathrm{~mol}^{-1}$ and between compounds $P$ and $S$ is $172.5 \mathrm{~g} \mathrm{~mol}^{-1}$.

    ($1$)The number of heteroatoms present in one molecule of $R$ is. . . . .  .

    [Use: Molar mass (in g mol ${ }^{-1}$ ): $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$

    Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]

    ($2$)The total number of carbon atoms and heteroatoms present in one molecule of $S$. . . . . .

    [Use: Molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ ]: $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$

    Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms

    Give the answer quetion ($1$) and ($2$)

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  • 2
    The amine formed from an amide by means of bromine and alkali has
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  • 3
    Ethylamine can be obtained by the
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  • 4
    Which of the following reaction does not involve Hoffmann Bromamide degradation ?
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  • 5
    Nitrobenzene gives $N- $ phenylhydroxylamine by
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  • 6
    Consider the following :
    $CH_3-CH_2-NH_2$           $Ph-CH_2-NH_2$       $Ph—NH_2$ 

                $(I) $                                     $(II)$                        $(III)$
    Correct order of their basic strength is :

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  • 7
    Reductive amination of $A$ forms :

    $A$ :

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  • 8
    The final product $(IV)$ obtained in the reaction sequence

    $Toluene\,\, \xrightarrow[{2.\,{H^ + }}]{{1.\,KMn{O_4}/O{H^ - }}}I\xrightarrow{{SOC{l_2}}}II\xrightarrow{{N{H_3}}}III\xrightarrow{{OB{r^ - }}}IV$ is

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  • 9
    Which of the following is incorrect
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  • 10
    Following tetrapeptide can be represented as

    $( F , L , D , Y , I , Q , P$ are one letter codes for amino acids)

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