5. Co-ordination chemistry — Chemistry STD 12 Science — Question

$(A)$ Over all order of this reaction is one

$(B)$ Order of this reaction can't be determined

$(C)$ In region$-I$ and $III$, the reaction is of first and zero order respectively

$(D)$ In region$-II$, the reaction is of first order

$(E)$ In region$-II$, the order of reaction is in the range of $0.1$ to $0.9$.

A solution $\mathrm{M}$ is prepared by mixing ethanol and water. The mole fraction of ethanol in the mixture is $0.9$ .

Given: Freezing point depression constant of water $\left(\mathrm{K}_{\mathrm{f}}^{\text {rate }}\right)=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Freezing point depression constant of ethanol $\left(\mathrm{K}_{\mathrm{f}}^{\text {ethunol }}\right)=2.0 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Boiling point elevation constant of water $\left(\mathrm{K}_{\mathrm{b}}^{\text {nate }}\right)=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Boiling point elevation constant of ethanol $\left(\mathrm{K}_{\mathrm{b}}^{\text {ethanol }}\right)=1.2 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Standard freezing point of water $=273 \mathrm{~K}$

Standard freezing point of ethanol $=155.7 \mathrm{~K}$

Standard boiling point of water $=373 \mathrm{~K}$

Standard boiling point of ethanol $=351.5 \mathrm{~K}$

Vapour pressure of pure water $=32.8 \mathrm{~mm} \mathrm{Hg}$

Vapour pressure of pure ethanol $=40 \mathrm{~mm} \mathrm{Hg}$

Molecular weight of water $=18 \mathrm{~g} \mathrm{~mol}^{-1}$

Molecular weight of ethanol $=46 \mathrm{~g} \mathrm{~mol}^{-1}$

In answering the following questions, consider the solutions to be ideal dilute solutions and solutes to be non-volatile and nondissociative.

$1.$ The freezing point of the solution ${M}$ is

$(A)$ $268.7 \mathrm{~K}$ $(B)$ $268.5 \mathrm{~K}$

$(C)$ $234.2 \mathrm{~K}$ $(D)$ $150.9 \mathrm{~K}$

$2.$ The vapour pressure of the solution ${M}$ is

$(A)$ $39.3 \mathrm{~mm} \mathrm{Hg}$ $(B)$ $36.0 \mathrm{~mm} \mathrm{Hg}$

$(C)$ $29.5 \mathrm{~mm} \mathrm{Hg}$ $(D)$ $28.8 \mathrm{~mm} \mathrm{Hg}$

$3.$ Water is added to the solution ${M}$ such that the fraction of water in the solution becomes $0.9$ . The boiling point of this solution is

$(A)$ $380.4 \mathrm{~K}$ $(B)$ $376.2 \mathrm{~K}$

$(C)$ $375.5 \mathrm{~K}$ $(D)$ $354.7 \mathrm{~K}$

Give the answer question $1,2$ and $3.$

Statement I : $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$ is a homoleptic complex whereas $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$is a heteroleptic complex.

Statement II : Complex $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$ has only one kind of ligands but $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}$has more than one kind of ligands.

In the light of the above statements, choose the correct answer from the options given below.