- A$NaCl < N{H_4}Cl < NaCN < HCl$
- B$HCl < NaCl < NaCN < N{H_4}Cl$
- C$NaCN < N{H_4}Cl < NaCl < HCl$
- ✓$HCl < N{H_4}Cl < NaCl < NaCN$
$NaCN $ undergoes anionic hydrolysis hence $ pH $ is $>7.$
$HCl$ is strong acid and $NaCl$ is neutral solution.
Hence the $pH$ of given solutions will increases.
$HCl < NaCl < NaCN < N{H_4}Cl$
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$(a)$ $CO < C{O_2} < CO_3^{2 - }$ $ \Rightarrow $ Bond length
$(b)$ ${O_2} < {O_3} < O_2^{ - 2}$ $ \Rightarrow $ Bond length
$(c)$ ${N_2} < N_2^ + $ $ \Rightarrow $ Bond energy
$(A)$ $CO _2, C _2 H _4, NO$ and $HCl$
$(B)$ $NO _2, O _3, HCl$ and $H _2 SO _4$
$(C)$ $BCl _3, NO , NO _2$ and $H _2 SO _4$
$(D)$ $CO _2, BCl _3, O _3$ and $C _2 H _4$
Statement-$I$: Since fluorine is more electronegative than nitrogen, the net dipole moment of $\mathrm{NF}_3$ is greater than $\mathrm{NH}_3$.
Statement-$II$: In $\mathrm{NH}_3$, the orbital dipole due to lone pair and the dipole moment of $\mathrm{NH}$ bonds are in opposite direction, but in $\mathrm{NF}_3$ the orbital dipole due to lone pair and dipole moments of $N-F$ bonds are in same direction. In the light of the above statements. Choose the most appropriate from the options given below.
because
$STATEMENT$-$2$: The small size of $\mathrm{B}^{3+}$ favours formation of covalent bond.