- A$\frac{\pi }{3}$
- B$\frac{\pi }{4}$
- C$\frac{\pi }{6}$
- ✓$\frac{\pi }{2}$
$\overrightarrow{\mathrm{AC}}=\overrightarrow{\mathrm{OC}}-\overrightarrow{\mathrm{OA}}=2 a+3 b-a=a+3 b$
Let $\theta$ be the angle between $\overrightarrow{\mathrm{BD}}$ and $\overrightarrow{\mathrm{AC}}$
Then $\cos \theta = \frac{{\overrightarrow {{\rm{BD}}} \cdot \overrightarrow {\overline {{\rm{AC}}} } }}{{|\overrightarrow {{\rm{BD}}} ||\overrightarrow {{\rm{AC}}} |}} = \frac{{|{\rm{a}}{|^2} - 9|{\rm{b}}{|^2}}}{{|\overrightarrow {{\rm{BD}}} \overrightarrow {{\rm{AC}}} |}}$
$=\frac{9|\mathrm{b}|^{2}-9|\mathrm{b}|^{2}}{|\overrightarrow{\mathrm{BD}}||\overrightarrow{\mathrm{AC}}|},(\therefore|\mathrm{a}|=3|\mathrm{b}|)$
$\Rightarrow \cos \theta=0 \Rightarrow \theta=\frac{\pi}{2}$
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