MCQ
The process with negative entropy change is
- ADissociation of $CaSO_4(s)$ to $CaO(s)$ and $SO_3(g)$
- BSublimation of dry ice
- CDissolution of iodine in water
- ✓Synthesis of ammonia from $N_2$ and $H_2$
$C{O_2}(s) \to C{O_2}(g)$
${I_2} \to {I_2}(aq)$
${N_2}(g) + 3{H_2}(g) \to 2N{H_3}(g)$
${N_2}(g) + 3{H_2} \leftrightarrow 2N{H_3}(g)$
$\Delta S = 2\Delta {S_{N{H_3}}} - [\Delta {S_{{N_2}}} + 3\Delta {S_{{H_2}}}]$
There is decrease in number of moles of $NH_3$ entropy is decreasing.
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${N_2}{O_4}(g)\, \to \,2N{O_2}(g)$
Data for the given reaction is
$\Delta H = +54\,kJ$ and $E_a = + 57.2\,kJ$
.......$kJ$

$(A)$ $O$ - $O$ bond lengths are equal.
$(B)$ Thermal decomposition of $O _3$ is endothermic.
$(C)$ $O _3$ is diamagnetic in nature.
$(D)$ $O _3$ has a bent structure.