The electronic configuration of
$B ^{+} \rightarrow \,1 s ^2 \,2 s ^2$
$Be ^{+} \rightarrow \,1 s ^2\, 2 s ^1$
$Mg ^{+} \rightarrow \,1 s ^2\, 2 s ^2\, 2 p ^6\, 3 s ^1$
$Si ^{+} \rightarrow \,1 s ^2 \,2 s ^2 \,2 p ^6 \,3 s ^2 \,3 p ^1$
So, in $B ^{+}$the electron is to be removed from completely filled $s$-subshell, which is difficult. Thus, the second ionization energy of boron is maximum.
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$A ( g ) \rightleftharpoons B ( g )+\frac{1}{2} C ( g )$
the relation between dissociation constant ( $K$ ), degree of dissociation $(\alpha)$ and equilibrium pressure $(p)$ is given by?
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(Given: Atomic number: $V , 23 ; Cr , 24 ; Fe , 26;Ni , 28)$
$V ^{3+} \cdot Cr ^{3+}, Fe ^{2+}, Ni ^{3+}$