MCQ
The shortest wavelength of $He^+$ ion in Balmer series is $x$, then longest wavelength in the paschen series of $Li^{2+}$ is
  • A
    $\frac{{36x}}{5}$
  • $\frac{{16x}}{7}$
  • C
    $\frac{{9x}}{5}$
  • D
    $\frac{{5x}}{9}$

Answer

Correct option: B.
$\frac{{16x}}{7}$
b
The wavelength of $H$ -like an atom is given by

$\frac{1}{\lambda}=R Z^{2}\left[\frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}}\right]$

For shortest wavelength $x$ of Paschen series $n_{2}=\infty$ and $n_{1}=3$

$\frac{1}{x}=R(3)^{2}\left[\frac{1}{3^{2}}-\frac{1}{\infty^{2}}\right]$

$\Rightarrow x=\frac{9}{9 R}=\frac{1}{R}$

For longest wavelength of Paschen series $n_{2}=4$ and $n_{1}=3$

$\frac{1}{\lambda}=R(3)^{2}\left[\frac{1}{3^{2}}-\frac{1}{4^{2}}\right]$

$\Rightarrow \frac{1}{\lambda}=R(3)^{2}\left[\frac{(16-9)}{16 \times 9}\right]$

$\Rightarrow \lambda=\frac{16}{7 R}=\frac{16 x}{7}$

Hence, the correct option is $B$

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