MCQ
The state of hybridization of the central atom is not the same as in the others
  • $B$ in $BF_3$
  • B
    $O$ in $H_3O^+$
  • C
    $N$ in $NH_3$
  • D
    $P$ in $PCl_3$

Answer

Correct option: A.
$B$ in $BF_3$
a
In $\mathrm{BF}_{3}$, the ground state electronic configuration of Boron is $1 \mathrm{s}^{2} 2 \mathrm{s}^{2} 2 \mathrm{P} \mathrm{x}^{1}$. excited state electronic configuration is $1 \mathrm{s}^{2} 2 \mathrm{s}^{1} 2 \mathrm{P} \mathrm{x}^{1} 2 \mathrm{Py}^{1}$

One electron from one 's' orbital and two electrons from 'p' orbital overlaps with 'p' orbital electrons of Flourine to form three $\mathrm{sp}^{2}$ hybridised bonds. So, $\mathrm{BF}_{3}$ has sp $^{2}$ hybridisation.

Flourine (a) But in $\mathrm{H}_{3} \mathrm{O}^{+}, \mathrm{NH}_{3}$ and $\mathrm{P} \mathrm{Cl}_{3}$, the hybridisation involves one electron from 's $^{\prime}$ orbital, 3 electrons for ${ }^{\prime} \mathrm{p}^{\prime}$ orbitals in central orbital forming $\mathrm{sp}^{3}$ hybridisation.

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