MCQ
Transition metal complex with highest value of crystal field splitting $\left(\Delta_{0}\right)$ will be ........ .
  • A
    $\left[ Cr \left( H _{2} O \right)_{6}\right]^{3+}$
  • B
    $\left[ Mo \left( H _{2} O \right)_{6}\right]^{3+}$
  • C
    $\left[ Fe \left( H _{2} O \right)_{6}\right]^{3+}$
  • $\left[ Os \left( H _{2} O \right)_{6}\right]^{3+}$

Answer

Correct option: D.
$\left[ Os \left( H _{2} O \right)_{6}\right]^{3+}$
d
$CFSE$ of octahedral complexes with water is greater for $5 d$ series metal centre ion as compared to $3 d$ and $4 d$ series metal centre.

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Redox reactions play a pivotal role in chemistry and biology. The values of standard redox potential ( $\mathrm{E}^{\circ}$ ) of two half-cell reactions decide which way the reaction is expected to proceed. A simple example is a Daniel cell in which zinc goes into solution and copper gets deposited. Given below are a set of half-cell reactions (acidic medium) along with their $E^{\circ}$ ($V$ with respect to normal hydrogen electrode) values. 

$\mathrm{I}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{I}\ \ \   \mathrm{E}^{\circ}=0.54 $

$\mathrm{Cl}_2+2 \mathrm{e}^{-} \rightarrow 2 \mathrm{Cl}^{-} \ \ \  \mathrm{E}^{\circ}=1.36 $

$\mathrm{Mn}^{3+}+\mathrm{e}^{-} \rightarrow \mathrm{Mn}^{2+} \ \ \  \mathrm{E}^{\circ}=1.50 $

$\mathrm{Fe}^{3+}+\mathrm{e}^{-} \rightarrow \mathrm{Fe}^{2+} \ \ \  \mathrm{E}^{\circ}=0.77 $

$\mathrm{O}_2+4 \mathrm{H}^{+}+4 \mathrm{e}^{-} \rightarrow 2 \mathrm{H}_2 \mathrm{O} \ \ \  \mathrm{E}^{\circ}=1.23$

$1.$ Among the following, identify the correct statement.

$(A)$ Chloride ion is oxidized by $\mathrm{O}_2$

$(B)$ $\mathrm{Fe}^{2+}$ is oxidized by iodine

$(C)$ Iodide ion is oxidized by chlorine

$(D)$ $\mathrm{Mn}^{2+}$ is oxidized by chlorine

$2.$ While $\mathrm{Fe}^{3+}$ is stable, $\mathrm{Mn}^{3+}$ is not stable in acid solution because

$(A)$ $\mathrm{O}_2$ oxidises $\mathrm{Mn}^{2+}$ to $\mathrm{Mn}^{3+}$

$(B)$ $\mathrm{O}_2$ oxidises both $\mathrm{Mn}^{2+}$ and $\mathrm{Fe}^{2+}$ to $\mathrm{Fe}^{3+}$

$(C)$ $\mathrm{Fe}^{3+}$ oxidizes $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$

$(D)$ $\mathrm{Mn}^{3+}$ oxidises $\mathrm{H}_2 \mathrm{O}$ to $\mathrm{O}_2$

$3.$ Sodium fusion extract, obtained from aniline, on treatment with iron $(II)$ sulphate and $\mathrm{H}_2 \mathrm{SO}_4$ in presence of air gives a Prussian blue precipitate. The blue colour is due to the formation of

$(A)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$ $(B)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$

$(C)$ $\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_2$ $(D)$ $\mathrm{Fe}_3\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3$

Give the answer question $1,2$ and $3.$

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