MCQ
Transition metal compounds are usually colored. This is due to the electronic transition:
  • A
    From p-orbital to s-orbital.
  • B
    From d-orbital to s-orbital.
  • C
    From d-orbital to p-orbital.
  • D
    Within the d-orbitals.

Answer

  1. Within the d-orbitals.

Explanation:

Colour in transition series metal compounds arises due to two types of transitions. they are:

(a) Charge transfer transitions [Ligand-to-metal charge transfer (LMCT), Metal-to-ligand charge transfer]

(b) d−d transition

In transition metal complexes, all the d− orbitals do not possess same energy. So, electrons can jump from a lower energy d− orbital to a higher energy d− orbital, by absorbing energy. When it returns to the ground state, excess energy is released, and a corresponding wavelength is found in the visible region.

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